Search results for "Vibrational Spectra. Algebraic Approach."

Vibrational Spectra of Polyatomic Molecules through an Algebraic Approach

1987

The study of molecular oscillators may be performed with algebraic methods based upon dynamical chains and their realization in terms of boson operators. From the dynamical algebra U(p+1) for p equivalent oscillators, associated with stretching modes, the local, pseudo-normal and normal limits are obtained through appropriate subgroup chains and various realizations of the U(p+1) generators. Similar technics can be applied to bending modes. Application to XY4 molecules will be presented.

Symmetrized Local States and Effective Dipole Moment within a Rovibrational Cartesian Picture.

1997

Rovibrational interactions in the local-mode limit. The (n000) stretching overtone bands of spherical tops.

1993

Algebraic approach to vibrational spectra of tetrahedral molecules. First order infrared intensity model.

1995

International audience; The algebraic approach we have proposed to describe the vibrational stretching modes of polyatomic molecules (Leroy and Michelot, J. Mol. Spectrosc. 151, 71–96 (1992); Can. J. Phys. 72, 274–289 (1994)) is applied to the silane molecule for up to seven quanta. We then suggest a form of the dipole operator adapted to the (n000) local states by combining the strength of group theory method with the necessity of a compact formulation.